demo, C++ (vc++) - rextester

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#include <iostream>
#include <iomanip>

#include <boost/archive/binary_oarchive.hpp>
#include <boost/multiprecision/cpp_int.hpp>
#include <boost/multiprecision/cpp_int/serialize.hpp>
#include <boost/iostreams/device/back_inserter.hpp>
#include <boost/iostreams/stream_buffer.hpp>
#include <boost/iostreams/stream.hpp>

#include <boost/functional/hash.hpp>

namespace mp_hashing {
    namespace io = boost::iostreams;

struct hash_sink {
        hash_sink(size_t& seed_ref) : _ptr(&seed_ref) {}

typedef char         char_type;
        typedef io::sink_tag category;

std::streamsize write(const char* s, std::streamsize n) {
            boost::hash_combine(*_ptr, boost::hash_range(s, s+n));
            return n;
        }
      private:
        size_t* _ptr;
    };

template <typename T> struct hash_impl {
        size_t operator()(T const& v) const {
            using namespace boost;
            size_t seed = 0;
            {
                iostreams::stream<hash_sink> os(seed);
                archive::binary_oarchive oa(os, archive::no_header | archive::no_codecvt);
                oa << v;
            }
            return seed;
        }
    };
}

#include <unordered_map>
#include <boost/unordered_map.hpp>

namespace std {
    template <typename backend> 
    struct hash<boost::multiprecision::number<backend> > 
        : mp_hashing::hash_impl<boost::multiprecision::number<backend> > 
    {};

template <typename K, typename V>
    struct hash<std::pair<K, V> > 
    {
        size_t operator()(std::pair<K, V> const& pair) const {
            size_t seed = std::hash<K>{}(pair.first);
            boost::hash_combine(seed, pair.second);
            return seed;
        }
    };
}

int main() {
    using boost::multiprecision::cpp_int;

std::unordered_map<std::pair<cpp_int, int>, int>  m {
        { { cpp_int(1) << 111, -1 }, 1 },
        { { cpp_int(2) << 222, -2 }, 2 },
        { { cpp_int(3) << 333, -3 }, 3 },
    };

for (auto& p : m)
        std::cout << p.first.first << " -> " << p.second << "\n";
}

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Compilation time: 5,04 sec, absolute running time: 0,22 sec, absolute service time: 5,27 sec